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Electron- and hole-hopping amplitudes in a diatomic molecule

Phys.Rev. B48, 3327 (1993)
We calculate the hopping amplitudes for an electron and for a hole added to the molecule H2. We use a linear combination
of atomic orbitals approach and the Hartree approximation. The hopping amplitudes for electrons and holes are found to
be different, reflecting the fundamental electron-hole asymmetry of condensed matter. The physical origin of this result is
discussed. We study the dependence of hopping amplitudes on internuclear distance and on the nuclear charge Z (Z=1
for H2) and discuss the possible implication of our results to the understanding of superconductivity in solids.

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